MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION -- 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE -- 6810-01-210-0149
===================== Product Identification ===================== Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE MSDS Date:03/14/1990 FSC:6810 NIIN:01-210-0149 === Responsible Party === Company Name:MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:800-354-2050(PRESS 3)/314-982-5000 Emergency Phone Num:800-354-2050/314-539-1600 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA 313) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000PPM/1250STEL9495 Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 43000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:ANESTHETIC IF INHALED.INHALATION OF VERY HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION,CARDIAC ARRHYTHMIAS.CONTACT MAY CAUSE SKIN IRRITATION/DEFATTING;EYE IRRITATION/POSSIBLE EYE DAMAGE.NO INFORMAT ION FOUND ON INGESTION,MAY PRODUCE SIMILAR TO INHALATION.CHRONIC:PROLONGED/REPEATED EXPOSURE MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED-INCOORDINATION, CARDIAC ARRHYTHMIAS, DROWSINESS, EXCITEMENT. EYES-REDNESS, TEARING, DISCOMFORT. SKIN-DEFATTING, REDNESS, DISCOMFORT. INGESTED-NO INFORMATION FOUND. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR EYE DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE. ======================= First Aid Measures ======================= First Aid:IN ALL CASES CALL A PHYSICIAN. EYES-IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFI CIAL RESPIRATION AS NEEDED. INGESTED-IFCONSCIOUS, INDUCE VOMITING IMMEDIATELY BY GIVING WATER OR MILK & STICK FINGER DOWN THROAT. NOTE TO DR: DO NOT USE EPINEPHRINE! ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN PRESSURE DEMAND OR POSITIVE PRESSURE MODE AND FULL PROTECTIVE GEAR. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AND EVACUATE AREA. CLEAN-UP PERSONNEL REQUIRE CLOTHING AND RESPIRATORY PROTECTION. ELIMINATE ALL SOURCES OF IGNITION. CONTAIN & RECOVER. ABSORB WITH INERT MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM SOURCES OF IGNITION. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT WEAR CONTACT LENSES WHEN USING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:NITRILE, PVA. Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES. Other Protective Equipment:WEAR CLEAN, BODY COVERING CLOTHING. DLA-HMIS: EYE WASH. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ENVIRONMENTAL DATA: SARA 311/312-ACUTE, CHRONIC; SARA 313-1,12-TRICHLORO-1,2,2-TRIFLUOROETHANE, CAS# 70-13-1, 100%; SARA 302-RQ/NO, TPQ/NO; CERCLA 103/NO; RCRA 261.33/NO. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:117F,47C Melt/Freeze Pt:M.P/F.P Text:-33F,-36C Vapor Pres:334 Vapor Density:6.5 Spec Gravity:1.57 Evaporation Rate & Reference:0.3 (CCL4=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ETHEREAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS (POWDERED ALUMINUM, ZINC, BERYLLIUM, MAGNESIUM), HEAT AND OPEN FLAME. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC VAPORS AND GASES SUCH AS HALOGEN ACIDS, HALOGENS AND CARBONYL ALKALIES MAY BE RELEASED IF INVOLVED IN FIRE. Conditions to Avoid Polymerization:HTIS PRODUCT DOES NOT POLYMERIZE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE CONTAINERIZED AND DISPOSED IN A RCRA APPROVED FACILITY. DO NOT FLUSH TO SEWER! Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.